What are Nanofibers?

“Nanofibers are defined as fibers with diameters less than 100 nanometres the textile industry ,this definition is often extended to include fibers as large as 1000nm diameter.

Nanofibers range in diameter of 2-600 nanometres and are very difficult to see with the naked eye so they are studied using magnification.

Unique Properties of Nanofibers

  • Nanofibers have a very small size due to which they have unique physical and chemical properties
  • Nanofibers have a huge surface area compared to their volume so scientists have lots of surface to work with !
  • Huge surface area available on a nanofiber makes it very suitable for new technologies which require a smaller and smaller environment for chemical reactions to occur. Increase the surface area speeds up a chemical reaction.

Nanofiber layer

Nano layer is a 3-dimensional fibre composed of stacked web of nanofibers. Such nanofibers coatings and nano membranes are produced through proprietary electrospinning process using various polymers. The interconnected and porous nanofibers have enormous surface area for its volume and has shape of a mesh.

Due to these unique features, it is very thin and light weighted. It also has high penetrability and permeability, but is also effective at resisting liquid and wind. These properties are particularly advantageous for high efficiency filter materials, energy storage materials, tissue engineering, biomedical application, micro-electronic mechanical system materials, nano complex materials and other applications.

Further, by applying nano layer to regular textile, it enhances functionality to be used as technical textiles in various application.


Production of Nanofiber

Nanofibers can be produced by …

  1. Melt Spinning
  2. Interfacial polymerization
  3. Electrospinning

Melt Spinning

Some nanofibers can be made by melting polymers and spinning or shooting them through very samll holes.As the fibers spins out it stretches smaller and smaller

Cotton candy is made by heating syrup to a high temperature and then the liquid is spun out through tiny holes .as the fiber spins it is pulled thinner and thinner.It cooles,hardens and presto!! Cotton Candy !



The smallest nanofobers are made by ELCTRPSOINNING solution of polymers.These solutions are place in pipette or syringe with a small wire inserted.The wire will serve as an electrode which is hooked to high voltage power supply.

Acollection plate where fibers will land and deposit is attached to the ground of the power supply.


Electrospinning

Generally, polymeric nanofibers are produced by an electrospinning process.

Electrospinning is a process that spins fibers of diameters ranging from 10nm to several 100nm.This method has been known since 1934 when the first patent on electrospinning was filed. Fibers properties depend on field uniformity, Polymer viscosity, electric field strength and distance between nozzle and collector.

Advancements in microscopy such as scanning electron microscopy has enabled us to better understand the structure and morphology of the nanofibers.

An electric field pulls on a droplet of polymer solution at the tip of the syringe and pulls out a small liquid fiber.It is pulled thinner and thinner as it approches the collection plate.

Electropsinnng a polymer solution to produce nanofibers :

Polymer solution can be electrospun beasue of their long repeating units.


Process Control Parameters

Electrode Distance:

Too high : No fiber deposition
Too Low: Chance of Arching

Applied Voltage:

Too high : Chance of arching
Too Low: not enough pull to form fiber

Needle diameter:

Diameter of fiber changes

Polymer Concentration:

Too High: Viscosity will not allow fiber formation
Too Low: Beads of polymer will form

Flow Rate:

Too High: Beads form
Too Low: Inconsistent fiber deposition

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